Which of the following will give a white prec | vedclass

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(D) white precipitate with $AgNO_3$ is formed by the reaction of $Ag^+$ ions with $Cl^-$ ions to form $AgCl$. This reaction occurs readily if the $C-C

Vedclass · Accepted Answer

Both $A$ and $C$

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(D) white precipitate with $AgNO_3$ is formed by the reaction of $Ag^+$ ions with $Cl^-$ ions to form $AgCl$. This reaction occurs readily if the $C-Cl$ bond breaks easily to release $Cl^-$. In $3$-chlorocyclohex-$1$-ene $(A)$,the carbocation formed after the loss of $Cl^-$ is allylic,which is resonance-stabilized. In benzyl chloride $(C)$,the carbocation formed is benzylic,which is also highly resonance-stabilized. Chlorobenzene $(B)$ does not give a precipitate because the $C-Cl$ bond has partial double-bond character due to resonance,making it difficult to break. Therefore,both $A$ and $C$ readily give a white precipitate of $AgCl$ with $AgNO_3$.

Which of the following will give a white precipitate with $AgNO_3$?

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