Which of the following combinations will form a basic buffer solution?

  • A
    $50 \ mL$ of $0.1 \ M \ NaOH + 25 \ mL$ of $0.1 \ M \ CH_{3}COOH$
  • B
    $100 \ mL$ of $0.1 \ M \ CH_{3}COOH + 100 \ mL$ of $0.1 \ M \ NaOH$
  • C
    $100 \ mL$ of $0.1 \ M \ HCl + 200 \ mL$ of $0.1 \ M \ NH_{4}OH$
  • D
    $100 \ mL$ of $0.1 \ M \ HCl + 100 \ mL$ of $0.1 \ M \ NaOH$

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$40 \ mL$ of $0.1 \ M$ ammonia solution is mixed with $20 \ mL$ of $0.1 \ M \ HCl$. What is the $pH$ of the mixture? ($pK_b$ of ammonia solution is $4.74$).

Equal volumes of $0.5 \ N$ acetic acid and $0.5 \ N$ sodium acetate are mixed. What is the $pH$ of the resultant solution? $(pK_{a}$ of acetic acid $= 4.75)$

Which of the following is a buffer solution?

All the given solutions have the same concentration. Mixing equal volumes of which of the following will produce a buffer solution?
$A = NH_4Cl$; $B = CH_3COONa$; $C = NH_4OH$; $D = CH_3COOH$

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