Why is the test for nitrogen,sulphur,or halogens not carried out by the direct addition of reagents to an organic compound?

$A$ solution of $m-$chloroaniline,$m-$chlorophenol and $m-$chlorobenzoic acid in ethyl acetate was extracted initially with a saturated solution of $NaHCO_3$ to give fraction $A$. The left over organic phase was extracted with dilute $NaOH$ solution to give fraction $B$. The final organic layer was labelled as fraction $C$. Fractions $A$,$B$ and $C$ contain respectively

Which of the following compounds is not expected to show Lassaigne's test for nitrogen?

Which of the following compounds is added to the sodium extract before the addition of silver nitrate for the testing of halogens?

Match Column $-I$ with Column $-II$.

Column $-I$	Column $-II$
$(A).$ Dumas method	$(3).$ Nitrogen gas
$(B).$ Kjeldahl's method	$(5).$ Ammonium sulphate
$(C).$ Carius method	$(1).$ $AgNO_3$
$(D).$ Chromatography	$(2).$ Silica gel
$(E).$ Homolytic fission	$(4).$ Free radical

Which one of the following sets of elements can be detected using sodium fusion extract?