Zinc carbonate is precipitated from zinc sulphate solution by the addition of

The required amount of $KBr$ (molar mass $= 119 \ g/mol$) in grams to start the precipitation of $AgBr$ in $500 \ mL$ solution of $0.05 \ M \ AgNO_3$ will be :- ($K_{SP}$ of $AgBr = 5 \times 10^{-13}$)

The solubility of $BaSO_4$ in pure water (in $g \, L^{-1}$) is closest to
[Given: $K_{sp}$ for $BaSO_4$ is $1.0 \times 10^{-10}$ at $25^{\circ} C$. Molecular weight of $BaSO_4$ is $233 \, g \, mol^{-1}$]

What is the molar solubility of $Mn(OH)_2$ $(K_{sp} = 4.5 \times 10^{-14})$ in a buffer solution containing equal moles of $NH_4^+$ and $NH_3$ $(K_b = 1.8 \times 10^{-5})$?

Assign $A$,$B$,$C$,$D$ from the given type of reaction.
$CaSO_3 \downarrow + SO_2 + H_2O \longrightarrow Ca(HSO_3)_2$

The solubility product of a sparingly soluble salt $AX$ is $4.9 \times 10^{-13}$. What is its solubility in $mol \ dm^{-3}$?