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Zone refining is a technique used primarily for which one of the following processes?

When an alloy of silver and lead is rich in silver,which process is used for purification?

Which method of purification is represented by the following equation?
$Ti_{(s)} + 2I_{2(g)}$ $\xrightarrow{523 \ K} TiI_{4(g)}$ $\xrightarrow{1700 \ K} Ti_{(s)} + 2I_{2(g)}$

Explain:
$(i)$ Zone refining
$(ii)$ Column chromatography.

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Which method is used for the purification of $Ni$?

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