Which of the following will $NOT$ give the characteristic test for $Fe^{2+}$ or $Fe^{3+}$ ions?

The reaction of $Pb(NO_3)_2$ and $NaCl$ in water produces a precipitate that dissolves upon the addition of $HCl$ of appropriate concentration. The dissolution of the precipitate is due to the formation of

Which of the following complexes represents maximum stability?

$X$ is the number of electrons in $t_{2g}$ orbitals of the most stable complex ion among $[Fe(NH_3)_6]^{3+}$,$[Fe(Cl)_6]^{3-}$,$[Fe(C_2O_4)_3]^{3-}$ and $[Fe(H_2O)_6]^{3+}$. The nature of the oxide of vanadium of the type $V_2O_X$ is:

$5.33 \text{ g}$ of $CrCl_3 \cdot 6H_2O$, which is a $1:3$ electrolyte, is dissolved in water and passed through a cation exchanger. The chloride ions in the eluted solution, on treatment with $AgNO_3$, result in $8.61 \text{ g}$ of $AgCl$. The ratio of moles of complex reacted and moles of $AgCl$ formed is . . . . . . $\times 10^{-2}$. (Nearest integer) [Molar mass in $\text{g mol}^{-1}$: $Cr = 52, Ag = 108, Cl = 35.5, H = 1, O = 16$]

Which of the following ions forms a complex with a coordination number of $2$ in the presence of excess $CN^{-}$?