The isomerism exhibited by [Co(NH_3)_5(SO_4)] | vedclass

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Question

(B) The given compounds are $[Co(NH_3)_5(SO_4)]Br$ and $[Co(NH_3)_5(SO_4)]Cl$. These complexes differ in the counter ions ($Br^-$ and $Cl^-$) present

Vedclass · Accepted Answer

Ionization isomerism

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(B) The given compounds are $[Co(NH_3)_5(SO_4)]Br$ and $[Co(NH_3)_5(SO_4)]Cl$. These complexes differ in the counter ions ($Br^-$ and $Cl^-$) present outside the coordination sphere. When these complexes dissolve in water,they produce different ions in the solution. This type of isomerism,where the counter ion is exchanged with a ligand from the coordination sphere or simply differs in the counter ion,is known as ionization isomerism.

The isomerism exhibited by $[Co(NH_3)_5(SO_4)]Br$ and $[Co(NH_3)_5(SO_4)]Cl$ is of the ........ type.

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