$A$ mixture $X$ containing $0.02 \, mol$ of $[Co(NH_3)_5SO_4]Br$ and $0.02 \, mol$ of $[Co(NH_3)_5Br]SO_4$ is dissolved in water to make a $2 \, L$ solution.
$1 \, L \, of \, X + \text{Excess of } AgNO_3 \rightarrow Y \, mol \, of \, ppt.$
$1 \, L \, of \, X + \text{Excess of } BaCl_2 \rightarrow Z \, mol \, of \, ppt.$
Then $Y$ and $Z$ are respectively ...............
$1 \, L \, of \, X + \text{Excess of } AgNO_3 \rightarrow Y \, mol \, of \, ppt.$
$1 \, L \, of \, X + \text{Excess of } BaCl_2 \rightarrow Z \, mol \, of \, ppt.$
Then $Y$ and $Z$ are respectively ...............
- A$0.01, 0.01$
- B$0.02, 0.01$
- C$0.01, 0.02$
- D$0.02, 0.02$
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Write down the $IUPAC$ name for each of the following complexes and indicate the oxidation state,electronic configuration,and coordination number. Also,give the stereochemistry and magnetic moment of the complex:
$(i)$ $K[Cr(H_2O)_2(C_2O_4)_2] \cdot 3H_2O$
$(ii)$ $[Co(NH_3)_5Cl]Cl_2$
$(iii)$ $CrCl_3(py)_3$
$(iv)$ $Cs[FeCl_4]$
$(v)$ $K_4[Mn(CN)_6]$
$(i)$ $K[Cr(H_2O)_2(C_2O_4)_2] \cdot 3H_2O$
$(ii)$ $[Co(NH_3)_5Cl]Cl_2$
$(iii)$ $CrCl_3(py)_3$
$(iv)$ $Cs[FeCl_4]$
$(v)$ $K_4[Mn(CN)_6]$
Difficult
View SolutionFor the given aqueous reaction,which of the statement$(s)$ is (are) true?
$2KI + 2K_3[Fe(CN)_6] \xrightarrow{H_2SO_4} I_2 + 2K_4[Fe(CN)_6]$
$(A)$ The first reaction is a redox reaction.
$(B)$ White precipitate is $K_2Zn_3[Fe(CN)_6]_2$.
$(C)$ Addition of filtrate to starch solution gives blue colour.
$(D)$ White precipitate is soluble in $NaOH$ solution.
$2KI + 2K_3[Fe(CN)_6] \xrightarrow{H_2SO_4} I_2 + 2K_4[Fe(CN)_6]$
$(A)$ The first reaction is a redox reaction.
$(B)$ White precipitate is $K_2Zn_3[Fe(CN)_6]_2$.
$(C)$ Addition of filtrate to starch solution gives blue colour.
$(D)$ White precipitate is soluble in $NaOH$ solution.
The volume (in $mL$) of $0.125\; M\; AgNO_{3}$ required to quantitatively precipitate chloride ions in $0.3\; g$ of $[Co(NH_{3})_{6}]Cl_{3}$ is (Given: $M_{[Co(NH_{3})_{6}]Cl_{3}} = 267.46\; g/mol$,$M_{AgNO_{3}} = 169.87\; g/mol$).
Which of the following orders is not correct?
The equation which is balanced and represents the correct product$(s)$ is:
DifficultJEE MAIN 2014
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