Explain stereoisomerism in coordination compounds.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Stereoisomerism arises in compounds that have the same chemical formula and chemical bonds but differ in their spatial arrangement of atoms or groups.
Geometric Isomerism:
For square planar complexes of the type $[ML_4]$: This type of isomerism arises due to different possible arrangements of ligands in heteroleptic complexes.
In complexes with coordination number $4$,square planar complexes with the formula $[MX_2L_2]$ exhibit two isomers: the $cis$ isomer,where two $X$ ligands are adjacent to each other,and the $trans$ isomer,where they are opposite to each other.
Other square planar complexes of the type $[MABXL]$ can also show three isomers (two $cis$ and one $trans$). This type of isomerism is not possible in tetrahedral geometry.
For octahedral complexes of the type $[ML_6]$: In complexes with the formula $[MX_2L_4]$,the two $X$ ligands can be oriented in either $cis$ or $trans$ positions relative to each other.
This type of isomerism also arises in complexes with the formula $[MX_2(L-L)_2]$ when bidentate ligands $(L-L)$ (e.g.,$en = NH_2CH_2CH_2NH_2$) are present.
Another type of geometric isomerism arises in octahedral complexes of the type $[Ma_3b_3]$,such as $[Co(NH_3)_3(NO_2)_3]$. If the three donor atoms of the same ligands occupy adjacent corners of an octahedral face,we obtain the facial $(fac)$ isomer.

Explore More

Similar Questions

The spin-only magnetic moment of a divalent ion in aqueous solution (atomic number $29$) is ...... $BM.$

The correct order of intensity of colors of the compounds is:

Which of the following are paramagnetic?
$A$. $[NiCl_4]^{2-}$
$B$. $Ni(CO)_4$
$C$. $[Ni(CN)_4]^{2-}$
$D$. $[Ni(H_2O)_6]^{2+}$
$E$. $Ni(PPh_3)_4$
Choose the correct answer from the options given below:

Match List-$I$ with List-$II$ :-
List-$I$ (Coordination compounds) List-$II$ (Number of unpaired electrons)
$A$. $[Cr(CN)_6]^{3-}$ $I$. $0$
$B$. $[Fe(H_2O)_6]^{2+}$ $II$. $3$
$C$. $[Co(NH_3)_6]^{3+}$ $III$. $2$
$D$. $[Ni(NH_3)_6]^{2+}$ $IV$. $4$

Choose the correct answer from the options given below :-

Which of the following complexes will exhibit optical isomerism?

Difficult
View Solution

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo