$CoSO_{4}Cl \cdot 5NH_{3}$ exists in two isomeric forms '$A$' and '$B$'. Isomer '$A$' reacts with $AgNO_{3}$ to give white precipitate,but does not react with $BaCl_{2}$. Isomer '$B$' gives white precipitate with $BaCl_{2}$ but does not react with $AgNO_{3}$. Answer the following questions.
$(i)$ Identify '$A$' and '$B$' and write their structural formulas.
$(ii)$ Name the type of isomerism involved.
$(iii)$ Give the $IUPAC$ name of '$A$' and '$B$.'

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(A) Isomer '$A$' reacts with $AgNO_{3}$ to give white precipitates,indicating the presence of $Cl^{-}$ ions in the ionisation sphere.
$\therefore A = [Co(NH_{3})_{5}(SO_{4})]Cl$
Isomer '$B$' reacts with $BaCl_{2}$,indicating the presence of $SO_{4}^{2-}$ ions in the ionisation sphere.
$\therefore B = [Co(NH_{3})_{5}Cl](SO_{4})$
$(ii)$ The type of isomerism is Ionisation Isomerism.
$(iii)$ $IUPAC$ names:
$A$: Pentaamminesulphatocobalt$(III)$ chloride
$B$: Pentaamminechloridocobalt$(III)$ sulphate

Explore More

Similar Questions

Which of the following compounds does not exhibit paramagnetism?

Difficult
View Solution

The total number of possible isomers for $[Pt(NH_3)_4Cl_2]Br_2$ is . . . . . . .

Which of the following complex ions exhibits geometrical isomerism?

$[Co(NH_3)_4(NO_2)_2]Cl$ exhibits

Which of the following pairs of complexes are isomeric with each other but their aqueous solutions exhibit different molar conductivities?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo