Describe the preparation of alkyl halides by halogen exchange reactions.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Finkelstein Reaction: Alkyl iodides are often prepared by the reaction of alkyl chlorides or bromides with $NaI$ in dry acetone. This reaction is known as the Finkelstein reaction.
Reaction: $R-X + NaI \xrightarrow{\text{dry acetone}} R-I + NaX_{(s)}$
(where $X = Cl, Br$)
$NaCl$ or $NaBr$ formed precipitates in dry acetone,which facilitates the forward reaction according to Le Chatelier's principle.
$(b)$ Swarts Reaction: Alkyl fluorides are best prepared by heating an alkyl chloride or bromide in the presence of a metallic fluoride such as $AgF$,$Hg_2F_2$,$CoF_2$,or $SbF_3$. This reaction is known as the Swarts reaction.
Reaction: $H_3C-Br + AgF \rightarrow H_3C-F + AgBr$

Explore More

Similar Questions

Which of the following compounds is obtained by using the Finkelstein reaction?

The major product in the following reaction sequence is:

Ethanol is converted into ethyl chloride by reacting with

The product obtained when ethyl alcohol is distilled with bleaching powder is

$A$ gem-dichloride is formed in the reaction except:

Difficult
View Solution

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo