$Emf$ of the following cell at $298 \,K$ in $V$ is $x \times 10^{-2}$. $Zn | Zn^{2+}(0.1 \,M) || Ag^{+}(0.01 \,M) | Ag$. The value of $x$ is .... . (Rounded off to the nearest integer) [Given: $E^{0}_{Zn^{2+}/Zn} = -0.76 \,V$; $E^{0}_{Ag^{+}/Ag} = +0.80 \,V$; $\frac{2.303 RT}{F} = 0.059$]

  • A
    $147$
  • B
    $157$
  • C
    $188$
  • D
    $288$

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For the cell $Zn_{(s)} | Zn^{2+} (0.1 \ M) || Fe^{2+} (0.01 \ M) | Fe_{(s)}$ at $298 \ K$,$E_{cell} = 0.2905 \ V$. What is the equilibrium constant $(K_c)$ for the reaction $Zn_{(s)} + Fe^{2+}_{(aq)} \rightleftharpoons Zn^{2+}_{(aq)} + Fe_{(s)}$?

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In a cell,a copper electrode was used as a cathode. What is the electrode potential (in $V$) of the copper electrode dipped in $0.1 \ M \ Cu^{2+}$ solution at $298 \ K$?
$(E_{Cu^{2+}/Cu}^{\ominus} = 0.34 \ V; \frac{2.303 \ RT}{F} = 0.06 \ V)$

In the electrochemical cell $:$
$Zn \,|\,ZnSO_4\,(0.01\,M)\,||\,CuSO_4\,(1.0\,M)\,|\,Cu$
the $emf$ of this Daniell cell is $E_1.$ When the concentration of $ZnSO_4$ is changed to $1.0\,M$ and that of $CuSO_4$ changed to $0.01\,M,$ the $emf$ changes to $E_2.$ From the followings,which one is the relationship between $E_1$ and $E_2$ $?$ (Given,$RT/F = 0.059$)

Consider the cell
$Pt_{(s)} \mid H_2(g, 1\,atm) \mid H^{+}(aq, 1\,M) \parallel Fe^{3+}_{(aq)}, Fe^{2+}_{(aq)} \mid Pt_{(s)}$
When the potential of the cell is $0.712\,V$ at $298\,K$,the ratio $[Fe^{2+}] / [Fe^{3+}]$ is $.......$ (Nearest integer).
Given: $Fe^{3+} + e^- \longrightarrow Fe^{2+}$,$E^{\circ}_{Fe^{3+}/Fe^{2+}} = 0.771\,V$
$\frac{2.303 RT}{F} = 0.06\,V$

Calculate the cell potential at $298 \ K$ for the following cells:
$(a)$ $Cd \mid Cd^{2+}(0.02 \ M) \parallel H^{+}(1 \ M) \mid H_{2(g)}(1 \ bar) \mid Pt$ $\left[ E_{Cd^{2+} \mid Cd}^0 = -0.40 \ V \right]$
$(b)$ $Al \mid Al^{3+}(0.25 \ M) \parallel Zn^{2+}(0.15 \ M) \mid Zn_{(s)}$ $\left[ E_{Al^{3+} \mid Al}^0 = -1.66 \ V, E_{Zn^{2+} \mid Zn}^0 = -0.76 \ V \right]$

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