Consider the cell
$Pt_{(s)} \mid H_2(g, 1\,atm) \mid H^{+}(aq, 1\,M) \parallel Fe^{3+}_{(aq)}, Fe^{2+}_{(aq)} \mid Pt_{(s)}$
When the potential of the cell is $0.712\,V$ at $298\,K$,the ratio $[Fe^{2+}] / [Fe^{3+}]$ is $.......$ (Nearest integer).
Given: $Fe^{3+} + e^- \longrightarrow Fe^{2+}$,$E^{\circ}_{Fe^{3+}/Fe^{2+}} = 0.771\,V$
$\frac{2.303 RT}{F} = 0.06\,V$

  • A
    $30$
  • B
    $10$
  • C
    $20$
  • D
    $50$

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If the $E^{\circ}_{cell}$ for a given reaction has a negative value,which of the following gives the correct relationships for the values of $\Delta G^{\circ}$ and $K_{eq}$ ?

The cell potential for the following cell
$Pt \mid H_{2(g)} \mid H^{+}_{(aq)} \parallel Cu^{2+}(0.01 \, M) \mid Cu_{(s)}$
is $0.576 \, V$ at $298 \, K$. The $pH$ of the solution is $......$ (Nearest integer)

What is the reduction electrode potential $E$ of a $0.1 \, M$ solution of $M^{+}$ ions,given that the standard reduction potential $E^o_{RP} = -2.36 \, V$?

To find the standard potential of $M^{3+}/M$ electrode,the following cell is constituted:
$Pt | M | M^{3+} (0.001 \ mol \ L^{-1}) || Ag^{+} (0.01 \ mol \ L^{-1}) | Ag$
The $emf$ of the cell is found to be $0.421 \ V$ at $298 \ K$. The standard potential of the half-reaction $M^{3+} + 3e^{-} \to M$ at $298 \ K$ will be .............. $V$.
(Given $E^{o}_{Ag^{+}/Ag}$ at $298 \ K = 0.80 \ V$)

The Nernst equation is related to:

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