$KMnO_4$ is titrated with ferrous ammonium sulphate hexahydrate in the presence of dilute $H_2SO_4$. The number of water molecules produced for $2$ molecules of $KMnO_4$ is $..........$.

$100 \ mL$ of aqueous solution of $0.05 \ M$ $Cu^{2+}$ is added to $1 \ L$ of $0.1 \ M$ $KI$ solution. The resultant solution was titrated with $0.01 \ M$ $Na_2S_2O_3$ solution using starch indicator till blue color disappeared. What is the volume (in $mL$) of $Na_2S_2O_3$ used?

Given below are two statements: One is labelled as Assertion $A$ and the other is labelled as Reason $R$.
Assertion $A$: Permanganate titrations are not performed in the presence of hydrochloric acid.
Reason $R$: Chlorine is formed as a consequence of the oxidation of hydrochloric acid.
In the light of the above statements,choose the correct answer from the options given below.

Assertion : $K_2Cr_2O_7$ is used as a primary standard in volumetric analysis.
Reason : It has a good solubility in water.

$A$ $2.0 \, g$ sample containing $MnO_2$ is treated with $HCl$ liberating $Cl_2$. The $Cl_2$ gas is passed into a solution of $KI$ and $60.0 \, mL$ of $0.1 \, M \, Na_2S_2O_3$ is required to titrate the liberated iodine. The percentage of $MnO_2$ in the sample is $.....$ (Nearest integer).
[Atomic masses (in $u$): $Mn = 55, Cl = 35.5, O = 16, I = 127, Na = 23, K = 39, S = 32$]

During the preparation of Mohr's salt solution (Ferrous ammonium sulphate),which of the following acid is added to prevent hydrolysis of $Fe^{2+}$ ion?