$C_6H_6 + 3O_3$ $\longrightarrow X \stackrel{Zn / H_2O}{}$ ${\longrightarrow} Y$; $X$ and $Y$ are respectively

The number of chlorine atoms present in the organic products $X$ and $Y$ of the following reactions, respectively, are:
$\text{Benzene} + 6Cl_2 \xrightarrow[\text{dark, cold}]{\text{Anhydr. } AlCl_3} X$
$\text{Benzene} + 3Cl_2 \xrightarrow{UV, 500 \text{ K}} Y$

Which of the following statements are correct?
$I$. In nitrating mixture,nitric acid participates as an acid.
$II$. $\sigma$-complex is the intermediate substance in electrophilic substitution of benzene.
$III$. Benzene on Friedel-Crafts alkylation with $n$-propyl chloride gives isopropyl benzene.

Consider the reaction sequence below:
Anisole $\xrightarrow[AlCl_3]{\text{Succinic anhydride}} A$ $\xrightarrow[\text{Clemmensen's reduction}]{\text{Cyclization}} X$
Identify $X$.

Among the following compounds,the one that is most reactive towards electrophilic nitration is

At what angle are the carbon atoms arranged in a benzene molecule?