Which thermochemical reaction is correct?

The lowest value of heat of neutralization is obtained for

Calculate the standard enthalpy change of the reaction: $C_2H_{2(g)} + \frac{5}{2}O_{2(g)} \rightarrow 2CO_{2(g)} + H_2O_{(\ell)}$ given the following standard enthalpies of formation:
$\Delta_fH^{\circ}(CO_2) = -393 \ kJ \ mol^{-1}$
$\Delta_fH^{\circ}(H_2O) = -286 \ kJ \ mol^{-1}$
$\Delta_fH^{\circ}(C_2H_2) = 227 \ kJ \ mol^{-1}$

The heat evolved in the combustion of benzene is given by the equation $C_6H_{6(l)} + 7.5 O_{2(g)} \to 3H_2O_{(l)} + 6CO_{2(g)}$,$\Delta H = -781.0 \ kcal \ mol^{-1}$. Which of the following quantities of heat energy will be evolved when $39 \ g$ of benzene is burnt in an open container?

Hess's law is applicable for the determination of heat of

Consider the reactions:
$C_{(s)} + 2H_{2(g)} \to CH_{4(g)}, \Delta H = -x \ kcal$
$C_{(g)} + 4H_{(g)} \to CH_{4(g)}, \Delta H = -x_1 \ kcal$
$CH_{4(g)} \to CH_{3(g)} + H_{(g)}, \Delta H = +y \ kcal$
The bond energy of $C-H$ bond is: