Which equation represents the $1/4^{th}$ life for a first-order reaction?

For which of the following reactions is the half-life period independent of the initial concentration of the reactant?

Which one of the following plots is correct for a first order reaction?

For an elementary reaction,$X_{(g)} \rightarrow Y_{(g)} + Z_{(g)}$,the $t_{1/2}$ is $10 \text{ minutes}$. In what period of time would the concentration of $X$ be reduced to $10 \%$ of its original concentration?

$A ( g ) \rightarrow 2 B ( g ) + C ( g )$ is a first order reaction. The initial pressure of the system was found to be $800 \ mm \ Hg$ which increased to $1600 \ mm \ Hg$ after $10 \ min$. The total pressure of the system after $30 \ min$ will be . . . . . . $mm \ Hg$. (Nearest integer)

When methyl acetate is hydrolyzed in $0.05 \, M$ $HCl$,the reaction occurs as follows: $CH_3COOCH_3 + H_2O \rightarrow CH_3COOH + CH_3OH$. $A$ $25 \, mL$ sample of the reaction mixture is taken at different time intervals,added to ice to stop the reaction,and then titrated with $0.05 \, M$ $NaOH$ solution. Prove that the reaction is first order using the data provided below:

Time (minute)	$0$	$20$	$75$	$120$	$\infty$
Volume of $0.05 \, M$ $NaOH$ ($V_t$ in $mL$)	$24.40$	$25.82$	$29.35$	$31.75$	$47.50$