Solid $Ba(NO_3)_2$ is gradually added to a $1.0 \times 10^{-4} \, M \, Na_2CO_3$ solution. At what concentration of $Ba^{2+}$ will precipitation start? (Given $K_{sp}$ for $BaCO_3 = 5.1 \times 10^{-9}$)

  • A
    $8.1 \times 10^{-8} \, M$
  • B
    $8.1 \times 10^{-7} \, M$
  • C
    $4.1 \times 10^{-5} \, M$
  • D
    $5.1 \times 10^{-5} \, M$

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