Which of the following statements is incorrect?

  • A
    Raoult's law states that the vapor pressure of a component over a solution is proportional to its mole fraction.
  • B
    The osmotic pressure $(\pi)$ of a solution is given by the equation $\pi = MRT$,where $M$ is the molarity of the solution.
  • C
    For $0.01 \ M$ aqueous solutions of each substance,the correct order of osmotic pressure is $BaCl_2 > KCl > CH_3COOH > \text{sucrose}$.
  • D
    Two solutions of sucrose prepared in different solvents with the same molality will have the same depression in freezing point.

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Similar Questions

If a $1 \ m$ solution of benzoic acid in benzene has a freezing point depression of $2.56 \ ^{\circ}C$ $(K_f = 5.12 \ ^{\circ}C \ kg \ mol^{-1})$ and a boiling point elevation of $2.53 \ ^{\circ}C$ $(K_b = 2.53 \ ^{\circ}C \ kg \ mol^{-1})$,select the correct statement$(s)$:
Statement $I$: There is dimer formation when undergoing freezing.
Statement $II$: There is no change when undergoing boiling.
Statement $III$: Reverse of $I$ and $II$.
Statement $IV$: Dimer formation in freezing and boiling state.

Distilled water boils at $373.15 \ K$ and freezes at $273.15 \ K$. $A$ solution of glucose in distilled water boils at $373.202 \ K$. What is the freezing point (in $K$) of the same solution? (For water, $K_{b}=0.52 \ K \ kg \ mol^{-1}, \ K_{f}=1.86 \ K \ kg \ mol^{-1}$)

$P_A = (235y - 125xy) \, \text{mm of Hg}$. $P_A$ is the partial pressure of $A$,$x$ is the mole fraction of $B$ in the liquid phase in the mixture of two liquids $A$ and $B$,and $y$ is the mole fraction of $A$ in the vapour phase. Then $P^o_B$ in $\text{mm of Hg}$ is:

The solubility product of a sparingly soluble $AB_2$ salt is $2.56 \times 10^{-4} \ M^3$ at $25^{\circ} C$. The $K_f$ of water is $1.8 \ K \ kg \ mol^{-1}$. The depression in freezing point of a saturated solution of $AB_2$ is (in $K$)

$1 \, \text{mole}$ of liquid $A$ and $2 \, \text{moles}$ of liquid $B$ make a solution having an observed vapour pressure of $42 \, \text{torr}$. The vapour pressures of pure $A$ and pure $B$ are $45 \, \text{torr}$ and $36 \, \text{torr}$ respectively. The described solution:

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