What is the freezing point (in $^\circ C$) of a solution containing $0.1 \ g$ of $K_3[Fe(CN)_6]$ (molar mass = $329 \ g \ mol^{-1}$) in $100 \ g$ of water? (Given $K_f = 1.86 \ K \ kg \ mol^{-1}$)

  • A
    $-2.3 \times 10^{-2}$
  • B
    $-5.7 \times 10^{-2}$
  • C
    $-5.7 \times 10^{-3}$
  • D
    $-1.2 \times 10^{-2}$

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The measured osmotic pressure of a solution prepared by dissolving $17.4 \ mg$ of $K_2SO_4$ in $2 \ L$ of water at $27^{\circ} C$ is $3.735 \times 10^{-3} \ bar$. The van't Hoff factor is $(R = 0.083 \ L \ bar \ K^{-1} \ mol^{-1}$; atomic weights $K = 39, S = 32, O = 16)$.

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