The solubility of carbonates of the alkaline earth metals decreases down the group. This is due to a decrease in which of the following?

  • A
    Hydration energy of cations
  • B
    Inter-ionic attraction
  • C
    Entropy of solution formation
  • D
    Lattice energy of the solid

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Discuss the general characteristics and gradation in properties of alkaline earth metals.

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The alkaline earth metal nitrate that does not crystallise with water molecules is

$BeO$ reacts with $HF$ in the presence of ammonia to give $[A]$,which on thermal decomposition produces $[B]$ and ammonium fluoride. The oxidation state of $Be$ in $[A]$ is $.....$.

Assertion : Both $Be$ and $Al$ can form complexes such as $BeF_4^{2-}$ and $AlF_6^{3-}$ respectively,$BeF_6^{3-}$ is not formed.
Reason : In case of $Be$,no vacant $d-$ orbitals are present in its outermost shell.

In the given reaction cycle,$X$,$Y$ and $Z$ respectively are:
$CaCl_2 + Na_2CO_3 \rightarrow X + Y$
$X \xrightarrow{Z} CaCl_2$

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