What is the major product of the reaction: $CH_3COOAg + Br_2 \xrightarrow{CS_2} \dots$?

Which of the following is used as a catalyst for preparing Grignard reagent?

Which of the following reaction$(s)$ can be used for the preparation of alkyl halides?
$I$. $CH_3CH_2OH + HCl \xrightarrow{Anh. ZnCl_2}$
$II$. $CH_3CH_2OH + HCl \rightarrow$
$III$. $(CH_3)_3COH + HCl \rightarrow$
$IV$. $(CH_3)_2CHOH + HCl \xrightarrow{Anh. ZnCl_2}$

Which one of the following reactions would be the best for the formation of $2-$bromobutane?
$(1)$ $CH_3CH=CHCH_2CH_3$ $\xrightarrow{HBr}$
$(2)$ $CH_3CH_2CH=CH_2$ $\xrightarrow{HBr}$
$(3)$ $CH_3CH=CHCH_3$ $\xrightarrow{Br_2}$
$(4)$ $CH_3CH_2CH=CH_2$ $\xrightarrow[Peroxide]{HBr}$

$Cl_2$ reacts with $CS_2$ in the presence of an $I_2$ catalyst to form:

Benzyl chloride $(C_6H_5CH_2Cl)$ is prepared from toluene by chlorination with ................?