Which of the following complexes does not mat | vedclass

Name: Exam Paper Generator | JEE NEET Paper Generator | Vedclass
Brand: Vedclass
Rating: 5 (35 reviews)

Question

(D) $1$. For $[Ni(CO)_4]$: $Ni$ is in $0$ oxidation state $(3d^8 4s^2)$. $CO$ is a strong field ligand,causing pairing. Hybridization is $sp^3$. (Corr

Vedclass · Accepted Answer

$(ii), (iii)$ and $(iv)$

Vedclass · Answer

(D) $1$. For $[Ni(CO)_4]$: $Ni$ is in $0$ oxidation state $(3d^8 4s^2)$. $CO$ is a strong field ligand,causing pairing. Hybridization is $sp^3$. (Correct)$2$. For $[Ni(CN)_4]^{2-}$: $Ni$ is in $+2$ oxidation state $(3d^8)$. $CN^-$ is a strong field ligand,causing pairing. Hybridization is $dsp^2$. (Incorrect,given as $sp^3$)$3$. For $[CoF_6]^{3-}$: $Co$ is in $+3$ oxidation state $(3d^6)$. $F^-$ is a weak field ligand,no pairing. Hybridization is $sp^3d^2$. (Incorrect,given as $d^2sp^3$)$4$. For $[Fe(CN)_6]^{3-}$: $Fe$ is in $+3$ oxidation state $(3d^5)$. $CN^-$ is a strong field ligand,causing pairing. Hybridization is $d^2sp^3$. (Incorrect,given as $sp^3d^2$)Thus,$(ii), (iii),$ and $(iv)$ do not match.

List-$I$ (Tetrahedral Complex)	List-$II$ (Electronic configuration)
$A$. $TiCl_4$	$I$. $e^2, t_2^0$
$B$. $[FeO_4]^{2-}$	$II$. $e^4, t_2^3$
$C$. $[FeCl_4]^{-}$	$III$. $e^0, t_2^0$
$D$. $[CoCl_4]^{2-}$	$IV$. $e^2, t_2^3$

Which of the following complexes does not match with the hybridization state of its metal ion?
$(i) [Ni(CO)_4], sp^3$
$(ii) [Ni(CN)_4]^{2-}, sp^3$
$(iii) [CoF_6]^{3-}, d^2sp^3$
$(iv) [Fe(CN)_6]^{3-}, sp^3d^2$

Similar Questions

$d^{2}sp^{3}$ hybridisation of the atomic orbitals gives

Which of the following statements is not true?

Predict the number of unpaired electrons in the square planar $[Pt(CN)_{4}]^{2-}$ ion.

The geometry possessed by $[Ni(CO)_4]$ is

Vedclass Test Series

Exam Paper Generator

Online Exam Module

Which of the following complexes does not match with the hybridization state of its metal ion?$(i) [Ni(CO)_4], sp^3$$(ii) [Ni(CN)_4]^{2-}, sp^3$$(iii) [CoF_6]^{3-}, d^2sp^3$$(iv) [Fe(CN)_6]^{3-}, sp^3d^2$