What is the IUPAC name of sodium nitroprussid | vedclass

Name: Exam Paper Generator | JEE NEET Paper Generator | Vedclass
Brand: Vedclass
Rating: 5 (35 reviews)

Question

(D) The formula of sodium nitroprusside is $Na_2[Fe(CN)_5NO]$.In this complex,the ligand $NO$ is present as $NO^+$ (nitrosonium ion).Let the oxidation

Vedclass · Accepted Answer

Sodium pentacyanonitrosylferrate $(III)$

Vedclass · Answer

(D) The formula of sodium nitroprusside is $Na_2[Fe(CN)_5NO]$.In this complex,the ligand $NO$ is present as $NO^+$ (nitrosonium ion).Let the oxidation state of $Fe$ be $x$.$2(+1) + x + 5(-1) + 1 = 0$$2 + x - 5 + 1 = 0$$x - 2 = 0$$x = +2$.Therefore,the $IUPAC$ name is sodium pentacyanonitrosylferrate $(II)$.Note: Option $(D)$ is often cited in older textbooks as $(III)$ due to the assumption of $NO$ as a neutral ligand,but the correct oxidation state of $Fe$ is $+2$ when $NO$ is treated as $NO^+$.

What is the $IUPAC$ name of sodium nitroprusside?

Similar Questions

Determine the oxidation state of $Cr$ in $[Cr(NH_3)_4Cl_2]^+$.

The $IUPAC$ name of the complex $[CrCl_2(H_2O)_4]NO_3$ is

What is the $IUPAC$ name of $Fe(CO)_5$?

The $IUPAC$ name of $[Co(NH_3)_6]Cl_3$ is

The $IUPAC$ name of $[Cr(en)_3]Cl_3$ is

Vedclass Test Series

Exam Paper Generator

Online Exam Module