Which of the following statements is incorrect?

  • A
    $[Ni(CO)_4]$ is tetrahedral and paramagnetic.
  • B
    $[Ni(CN)_4]^{2-}$ is square planar and diamagnetic.
  • C
    $[Ni(CO)_4]$ is tetrahedral and diamagnetic.
  • D
    $[NiCl_4]^{2-}$ is tetrahedral and paramagnetic.

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$[NiCl_{4}]^{2-}$ is paramagnetic while $[Ni(CO)_{4}]$ is diamagnetic though both are tetrahedral. Why?

Which of the following statements is incorrect regarding $[Ni(dmg)_2]$?

Which of the following statements is incorrect?

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Which of the following complexes exhibits $dsp^2$ hybridization?

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An aqueous solution of metal ion $M1$ reacts separately with reagents $Q$ and $R$ in excess to give tetrahedral and square planar complexes,respectively. An aqueous solution of another metal ion $M2$ always forms tetrahedral complexes with these reagents. Aqueous solution of $M2$ on reaction with reagent $S$ gives a white precipitate which dissolves in excess of $S$. The reactions are summarized in the scheme given below:
$1.$ $M1$,$Q$ and $R$,respectively are :
$(A)$ $Zn^{2+}, KCN$ and $HCl$
$(B)$ $Ni^{2+}, HCl$ and $KCN$
$(C)$ $Cd^{2+}, KCN$ and $HCl$
$(D)$ $Co^{2+}, HCl$ and $KCN$
$2.$ Reagent $S$ is :
$(A)$ $K_4[Fe(CN)_6]$
$(B)$ $Na_2HPO_4$
$(C)$ $K_2CrO_4$
$(D)$ $KOH$
Give the answer for question $1$ and $2$.

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