$A$ Beckmann thermometer is used to measure:

Which of the following mixtures is known as Proof Spirit (by volume)?

Match List-$I$ with List-$II$.

List-$I$	List-$II$
$A$. van't Hoff factor,$i$	$I$. Cryoscopic constant
$B$. $k_{f}$	$II$. Isotonic solutions
$C$. Solutions with same osmotic pressure	$III$. $\frac{\text{Normal molar mass}}{\text{Abnormal molar mass}}$
$D$. Azeotropes	$IV$. Solutions with same composition of vapour above it

Choose the correct answer from the options given below:

In which solution,solute is liquid and solvent is gas?

An aqueous solution freezes at $-2.55 \ ^oC$. What is its boiling point in $^oC$?
[$K_b(H_2O) = 0.52 \ K \ kg \ mol^{-1}, K_f(H_2O) = 1.86 \ K \ kg \ mol^{-1}$]

$100 \ mL$ of $1.5\%(w/v)$ solution of urea has an osmotic pressure of $6.0 \ atm$ and $100 \ mL$ of $3.42\%(w/v)$ solution of cane sugar has an osmotic pressure of $2.4 \ atm$. If the two solutions are mixed,the osmotic pressure of the resulting solution in $atm$ is (Assume that there is no reaction between urea and cane sugar).