$A$ certain gas obeys $P(V_{m}-b)=RT$. The value of $(\frac{\partial Z}{\partial P})_{T}$ is $\frac{xb}{RT}$. The value of $x$ is .... .
(Integer answer) ($Z$: compressibility factor)

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(C) The compressibility factor $Z$ is defined as $Z = \frac{PV_{m}}{RT}$.
Given the equation of state: $P(V_{m}-b) = RT$,we can write $PV_{m} - Pb = RT$.
Dividing by $RT$,we get $\frac{PV_{m}}{RT} - \frac{Pb}{RT} = 1$,which simplifies to $Z - \frac{Pb}{RT} = 1$,or $Z = 1 + \frac{Pb}{RT}$.
Now,we differentiate $Z$ with respect to $P$ at constant temperature $T$: $(\frac{\partial Z}{\partial P})_{T} = \frac{\partial}{\partial P}(1 + \frac{Pb}{RT}) = 0 + \frac{b}{RT} = \frac{1 \times b}{RT}$.
Comparing this with the given expression $\frac{xb}{RT}$,we find that $x = 1$.

Explore More

Similar Questions

$A$ gas such as carbon monoxide would be most likely to obey the ideal gas law at

When helium gas is allowed to expand into vacuum, a heating effect is observed. The reason for this is (assume $He$ as a non-ideal gas):

Maximum deviation from ideal gas behavior is expected from which of the following gases?

Under which one of the following conditions do real gases approach the ideal gas behaviour?

For real gases,the van der Waals equation is written as $\left( p + \frac{a n^2}{V^2} \right) (V - nb) = nRT$,where $a$ and $b$ are van der Waals constants. Two sets of gases are:
$(I)$ $O_2, CO_2, H_2, He$
$(II)$ $CH_4, O_2, H_2$
The gases given in set-$I$ are arranged in increasing order of $b$,and the gases given in set-$II$ are arranged in decreasing order of $a$. Select the correct order from the following:

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo