$A$ pink coloured salt turns blue on heating. The presence of which cation is most likely?

If $Pb^{2+}, Cu^{2+}, Al^{3+}, Cd^{2+}, Zn^{2+}$ radicals are present in an aqueous solution,and it reacts with $H^{+}/H_2S$,a precipitate is produced. The solution $(X)$ obtained after the removal of the precipitate is treated with excess $NaOH$. What is the result?

$A$ solution of a metal ion,when treated with $KI$,gives a red precipitate which dissolves in excess $KI$ to give a colourless solution. Moreover,the solution of the metal ion,on treatment with a solution of cobalt$(II)$ thiocyanate,gives rise to a deep blue crystalline precipitate. The metal ion is:

Passing $H_2S$ gas into a mixture of $Mn^{2+}, Ni^{2+}, Cu^{2+}$ and $Hg^{2+}$ ions in an acidified aqueous solution precipitates

Which of the following options is incorrect?

The reagent used in the qualitative analysis of the $IV^{th}$ group basic radicals is: