Arrange the following in the order of property indicated for each set:
$(i)$ $F_{2}, Cl_{2}, Br_{2}, I_{2}$ - increasing bond dissociation enthalpy.
$(ii)$ $HF, HCl, HBr, HI$ - increasing acid strength.
$(iii)$ $NH_{3}, PH_{3}, AsH_{3}, SbH_{3}, BiH_{3}$ - increasing base strength.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(A) $(i)$ Bond dissociation energy usually decreases on moving down a group as the atomic size increases. However,the bond dissociation energy of $F_{2}$ is lower than that of $Cl_{2}$ and $Br_{2}$ due to the small atomic size and interelectronic repulsions in fluorine. Thus,the increasing order is: $I_{2} < F_{2} < Br_{2} < Cl_{2}$.
$(ii)$ The bond dissociation energy of $H-X$ molecules decreases as the atomic size of $X$ increases. Since the $H-I$ bond is the weakest,$HI$ is the strongest acid. The increasing order is: $HF < HCl < HBr < HI$.
$(iii)$ On moving from nitrogen to bismuth,the atomic size increases and the electron density on the central atom decreases,reducing the availability of the lone pair. Thus,the basic strength decreases. The increasing order is: $BiH_{3} < SbH_{3} < AsH_{3} < PH_{3} < NH_{3}$.

Explore More

Similar Questions

$X_2$ is used in the refining of $Ti$ metal by the van Arkel method. $Y_2$ does not liberate $O_2$ from water and does not form $HY$ and $HOY$ with water. $X_2$ and $Y_2$ are respectively:

Explain the preparation of chlorine and describe the Deacon's process and electrolytic process for its production.

Difficult
View Solution

The property/properties that show irregularity in the first four elements of group-$17$ is/are:

The colour of the $X_2$ molecules of group $17$ elements changes gradually from yellow to violet down the group. This is due to
[$A$] the physical state of $X_2$ at room temperature changes from gas to solid down the group
[$B$] decrease in $HOMO-LUMO$ gap down the group
[$C$] decrease in $\pi^*-\sigma^*$ gap down the group
[$D$] decrease in ionization energy down the group

Which of the following is not a peroxy acid?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo