Calculate the $pH$ of a buffer solution containing $0.35 \ M$ weak acid and $0.70 \ M$ of its salt with a strong base if $pK_{a}$ is $4.56$.

Which one of the following pairs of solutions is not an acidic buffer?

$2 \ g$ acetic acid and $3 \ g$ sodium acetate are present in $100 \ mL$ aqueous solution. What will be the $pH$ of the solution if the ionisation constant of acetic acid is $1.8 \times 10^{-5}$?

$A$ buffer solution contains $100 \ mL$ of $0.01 \ M \ CH_3COOH$ and $200 \ mL$ of $0.02 \ M \ CH_3COONa$. If $700 \ mL$ of $1 \ M \ NaCl$ is added,what are the $pH$ values before and after the addition? $(pK_a = 4.74)$

$40 \ mL$ of $0.1 \ M$ ammonia solution is mixed with $20 \ mL$ of $0.1 \ M \ HCl$. What is the $pH$ of the mixture? ($pK_b$ of ammonia solution is $4.74$).

Assertion : Buffer system of carbonic acid and sodium bicarbonate is used for the precipitation of hydroxides of third group elements.
Reason : It maintains the $pH$ to a constant value,about $7.4.$