Calculate the heat produced in $kJ$ when $280 \ g$ of $CaO$ is completely converted to $CaCO_3$ by reaction with $CO_2$ at $27 \ ^{\circ}C$ and at constant volume :-
(Given) $\Delta H^o_f (CaCO_3, s) = -1207 \ kJ/mol$
$\Delta H^o_f (CaO, s) = -635 \ kJ/mol$
$\Delta H^o_f (CO_2, g) = -394 \ kJ/mol$ (in $kJ$)

  • A
    $800$
  • B
    $877.55$
  • C
    $500$
  • D
    $730$

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$28.0 \, L$ of $CO_2$ is produced on complete combustion of $16.8 \, L$ gaseous mixture of ethene $(C_2H_4)$ and methane $(CH_4)$ at $25^{\circ}C$ and $1 \, atm$. Heat evolved during the combustion process is $......... \, kJ$.
Given :
$\Delta H_C(CH_4) = -900 \, kJ \, mol^{-1}$
$\Delta H_C(C_2H_4) = -1400 \, kJ \, mol^{-1}$

$X \, g$ of ice at $0^{\circ} C$ is added to $340 \, g$ of water at $20^{\circ} C$. The final temperature of the resultant mixture is $5^{\circ} C$. The value of $X$ (in $g$) is closest to:
[Heat of fusion of ice $= 333 \, J / g$; specific heat of water $= 4.184 \, J / g \cdot K$]

The enthalpies of combustion of $S_{(s)}$ and $H_{2(g)}$ are $-300 \ kcal \ mol^{-1}$ and $-290 \ kcal \ mol^{-1}$ respectively. Given the following reactions:
$SO_{3(g)} + H_2O_{(l)} \rightarrow H_2SO_{4(l)}$; $\Delta H = -130 \ kcal \ mol^{-1}$
$SO_{2(g)} + 1/2 O_{2(g)} \rightarrow SO_{3(g)}$; $\Delta H = -100 \ kcal \ mol^{-1}$
$S_{(s)} + O_{2(g)} \rightarrow SO_{2(g)}$; $\Delta H = -300 \ kcal \ mol^{-1}$
$H_{2(g)} + 1/2 O_{2(g)} \rightarrow H_2O_{(l)}$; $\Delta H = -290 \ kcal \ mol^{-1}$
The enthalpy of formation of $H_2SO_{4(l)}$ is:

The volume of a gas decreases from $500 \ cc$ to $300 \ cc$ when a sample of gas is compressed by an average pressure of $0.6 \ atm$. During this process $10 \ J$ of heat is liberated. The change in internal energy is......$J$

Match the conditions and the temperature for the 'fusion' process of $H_2O_{(s)}$ at $1 \ atm$ pressure.
Condition Temperature
$(1)$. Spontaneous $(p)$. $273 \ K$
$(2)$. At equilibrium $(q)$. $260 \ K$
$(3)$. Non-spontaneous $(r)$. $280 \ K$

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