Compound (P) is formed by the acid-catalyzed | vedclass

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(C) The acid-catalyzed rearrangement of $1$-methyl-$1$-cyclohexyl hydrogen peroxide involves the protonation of the peroxide oxygen,followed by the mi

Vedclass · Accepted Answer

$CH_3-CO-(CH_2)_5-OH$

Vedclass · Answer

(C) The acid-catalyzed rearrangement of $1$-methyl-$1$-cyclohexyl hydrogen peroxide involves the protonation of the peroxide oxygen,followed by the migration of the ring carbon to the oxygen atom,leading to ring expansion and subsequent cleavage to form a ketone with a terminal hydroxyl group. The product is $6$-hydroxyhexan-$2$-one,which has the structure $CH_3-CO-(CH_2)_4-CH_2-OH$,or $CH_3-CO-(CH_2)_5-OH$. This compound gives a positive iodoform test due to the $CH_3-CO-$ group,a positive $2,4-DNP$ test due to the carbonyl group,and a positive test with $CrO_3$ due to the primary alcohol group.

Compound $(P)$ is formed by the acid-catalyzed rearrangement of $1$-methyl-$1$-cyclohexyl hydrogen peroxide. The reaction is shown below. Identify compound $(P)$.

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