Consider the following electrodes $P = Zn^{2+}(0.0001 \ M) / Zn$,$Q = Zn^{2+}(0.1 \ M) / Zn$,$R = Zn^{2+}(0.01 \ M) / Zn$,$S = Zn^{2+}(0.001 \ M) / Zn$. Given $E^{\circ}(Zn^{2+} / Zn) = -0.76 \ V$,the electrode potentials of the above electrodes in volts are in the order:

  • A
    $P > S > R > Q$
  • B
    $S > R > Q < P$
  • C
    $Q > R > S > P$
  • D
    $P > Q > R > S$

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Similar Questions

The $E^o$ for the cell $Zn|Zn^{2+}_{(aq)}||Cu^{2+}_{(aq)}|Cu$ is $1.10 \ V$ at $25 \ ^oC$. The equilibrium constant for the reaction $Zn + Cu^{2+}_{(aq)} \rightleftharpoons Cu + Zn^{2+}_{(aq)}$ is of the order of:

Write a note on the relation between Gibbs free energy and cell potential for a cell reaction.

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The standard $e.m.f.$ of a cell,involving one electron change is found to be $0.591 \ V$ at $25^{\circ} C$. The equilibrium constant of the reaction is :
$(F=96500 \ C \ mol^{-1} ; R=8.314 \ JK^{-1} \ mol^{-1})$

What must be the concentration of $Ag^{+}$ in an aqueous solution containing $Cu^{2+} = 1.0 \ M$ so that both the metals can be deposited on the cathode simultaneously? Given that $E^0_{Cu^{2+}/Cu} = 0.34 \ V$ and $E^0_{Ag^{+}/Ag} = 0.812 \ V$ at $T = 298 \ K$.

For the cell,$Mn_{(s)}|Mn_{(aq)}^{2+}(0.4\,M)||Sn_{(aq)}^{2+}(0.04\,M)|Sn_{(s)}$,calculate the free energy change $(\Delta G)$ at $298\,K$ in $kJ$.
Given: $E_{Mn^{2+}|Mn}^o = -1.18\,V$; $E_{Sn^{2+}|Sn}^o = -0.14\,V$; $\frac{2.303\,RT}{F} = 0.06$

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