Consider the following reversible first-order reaction of $X$ at an initial concentration $[X]_{0}$. The values of the rate constants are $K_{f} = 2 \ s^{-1}$ and $K_{b} = 1 \ s^{-1}$.
$X \underset{K_{b}}{\stackrel{K_{f}}{\rightleftharpoons}} Y$
Which of the following plots correctly represents the concentration of $X$ and $Y$ as a function of time?

Ammonia under a pressure of $15 \ atm$ at $27 \ ^{\circ}C$ is heated to $347 \ ^{\circ}C$ in a closed vessel in the presence of a catalyst. Under these conditions,$NH_3$ is partially decomposed according to the equation,$2NH_3 \rightleftharpoons N_2 + 3H_2$. The vessel is such that the volume remains constant,and the pressure increases to $50 \ atm$. Calculate the percentage of $NH_3$ actually decomposed.

Which one of the following statements is correct for a reversible reaction? $A$ catalyst

For a reaction taking place in a container in equilibrium with its surroundings,the effect of temperature on its equilibrium constant $K$ in terms of change in entropy is described by:

Attainment of the equilibrium $A_{(g)} \rightleftharpoons 3C_{(g)} + 2B_{(g)}$ gave the following graph. Find the correct option. $(\text{Percentage dissociation} = \text{fraction dissociated} \times 100)$

In a closed vessel of $1 \ L$ capacity,$2 \ mol$ of $N_2$ and $6 \ mol$ of $H_2$ are mixed. If at equilibrium $50\% \ N_2$ is converted into $NH_3$,then the value of $K_c$ for the reaction $N_{2(g)} + 3H_{2(g)} \rightleftharpoons 2NH_{3(g)}$ will be: