Which of the following statements is correct?

Among the compounds given below,the order of basicity is:
$(I)$ Piperidine
$(II)$ Pyridine
$(III)$ Morpholine
$(IV)$ Pyrrole

Consider the following reaction sequence starting from $p$-nitrotoluene:
$(i)$ $\text{Sn/HCl; OH}^-$
(ii) $(\text{CH}_3\text{CO})_2\text{O}$
(iii) $\text{Br}_2/\text{AlBr}_3$
(iv) $\text{H}_3\text{O}^+$
When the final product $(P)$ is subjected to Carius analysis using $\text{AgNO}_3$, $1.0 \text{ g}$ of the product $(P)$ will produce . . . . . . $\text{g}$ of the precipitate of $\text{AgBr}$. (Nearest Integer)
(Given: molar mass in $\text{g mol}^{-1}$: $\text{C} = 12, \text{H} = 1, \text{O} = 16, \text{N} = 14, \text{Br} = 80, \text{Ag} = 108$)

What are $X$ and $Y$ respectively in the following set of reactions?

The relative rate of reaction of the following amines with methyl iodide is:

Which of the following reactions will not give a primary amine?