Disorders of amino acid metabolism result in which of the following conditions?

Assertion $(S)$: The measure of disorder in a biological system is called free energy.
Reason $(R)$: The energy available in a biological system to perform work is called entropy.
$(A)$ Both $S$ and $R$ are true,and $R$ is the correct explanation of $S$.
$(B)$ Both $S$ and $R$ are true,but $R$ is not the correct explanation of $S$.
$(C)$ $S$ is true and $R$ is false.
$(D)$ $S$ is false and $R$ is true.
$(E)$ Both $S$ and $R$ are false.

Which match is true?

Vitamins are:

Which of the following is not used in biochemical processes?

The energy released by one molecule of $ATP$ is approximately: (in $kcal$)