Equal volumes of methanoic acid and sodium hydroxide are mixed. If $x$ is the heat of formation of water,then the heat evolved on neutralization is

Given,
$NO_{(g)} + O_{3(g)} \longrightarrow NO_{2(g)} + O_{2(g)}; \Delta H = -198.9 \, kJ/mol$
$O_{3(g)} \longrightarrow 3/2 O_{2(g)}; \Delta H = -142.3 \, kJ/mol$
$O_{2(g)} \longrightarrow 2O_{(g)}; \Delta H = +495.0 \, kJ/mol$
The enthalpy change $(\Delta H)$ for the following reaction is $..... \, kJ/mol$
$NO_{(g)} + O_{(g)} \longrightarrow NO_{2(g)}$

Diborane is formed from the elements as shown in equation $(i)$:
$2 B_{(s)} + 3 H_{2(g)} \longrightarrow B_2H_{6(g)} \dots (i)$
Given that:
$H_2O_{(l)} \longrightarrow H_2O_{(g)}, \quad \Delta H_1^{\circ} = 44 \, kJ$
$2 B_{(s)} + \frac{3}{2} O_{2(g)} \longrightarrow B_2O_{3(s)}, \quad \Delta H_2^{\circ} = -1273 \, kJ$
$B_2H_{6(g)} + 3 O_{2(g)} \longrightarrow B_2O_{3(s)} + 3 H_2O_{(g)}, \quad \Delta H_3^{\circ} = -2035 \, kJ$
$H_{2(g)} + \frac{1}{2} O_{2(g)} \longrightarrow H_2O_{(l)}, \quad \Delta H_4^{\circ} = -286 \, kJ$
The $\Delta H^{\circ}$ for the reaction $(i)$ is $..... \, kJ$.

Identify the $INVALID$ equation.

The values of bond enthalpy of $H_2$,$Cl_2$ and $HCl$ are $104$,$58$ and $103 \ kcal/mol$ respectively. Find the enthalpy of formation of $HCl_{(g)}$. Reaction: $\frac{1}{2}H_{2(g)} + \frac{1}{2}Cl_{2(g)} \to HCl_{(g)}$

Given that the bond energies of $N \equiv N$ is $946 \ kJ \ mol^{-1}$,$H-H$ is $435 \ kJ \ mol^{-1}$,$N-N$ is $159 \ kJ \ mol^{-1}$,and $N-H$ is $389 \ kJ \ mol^{-1}$,calculate the enthalpy of formation for the gas phase reaction $N_2 + 2H_2 \rightarrow N_2H_4$ in $kJ \ mol^{-1}$.