Explain enthalpy changes during phase transformations.

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(N/A) Standard enthalpy of fusion $(\Delta_{fus} H)$: The enthalpy change that accompanies the melting of one mole of a solid substance in its standard state is called the standard enthalpy of fusion. Melting is an endothermic process,so $\Delta_{fus} H$ is always positive.
$H_2O_{(s)} \rightarrow H_2O_{(l)}$; $\Delta_{fus} H = 6.00 \ kJ \ mol^{-1}$
Standard enthalpy of vaporization $(\Delta_{vap} H)$: The amount of heat required to vaporize one mole of a liquid at a constant temperature and under standard pressure $(1 \ bar)$ is called its standard enthalpy of vaporization.
$H_2O_{(l)} \rightarrow H_2O_{(g)}$; $\Delta_{vap} H = +40.79 \ kJ \ mol^{-1}$
Standard enthalpy of sublimation $(\Delta_{sub} H)$: The change in enthalpy when one mole of a solid substance sublimes directly into its vapour at a constant temperature and under standard pressure $(1 \ bar)$.
$CO_{2_{(s)}} \rightarrow CO_{2_{(g)}}$; $\Delta_{sub} H^o = 25.2 \ kJ \ mol^{-1}$
The magnitude of these enthalpy changes depends on the strength of the intermolecular interactions in the substance.
Substance$T_f / K$$\Delta_{fus} H / (kJ \ mol^{-1})$$T_b / K$$\Delta_{vap} H / (kJ \ mol^{-1})$
$N_2$$63.15$$0.72$$77.35$$5.59$
$NH_3$$195.40$$5.65$$239.73$$23.35$
$HCl$$159.0$$1.992$$188.0$$16.15$
$CO$$68.0$$6.836$$82.0$$6.04$
$CH_3COCH_3$$177.8$$5.72$$329.4$$29.1$
$CCl_4$$250.16$$2.5$$349.69$$30.0$
$H_2O$$273.15$$6.01$$373.15$$40.79$
$NaCl$$1081.0$$28.8$$1665.0$$170.0$
$C_6H_6$$278.65$$9.83$$353.25$$30.8$

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