Find the $emf$ of the cell in which the following reaction takes place at $298 \ K$ (in $V$):
$Ni_{(s)} + 2Ag^{+}(0.001 \ M) \rightarrow Ni^{2+}(0.001 \ M) + 2Ag_{(s)}$
(Given that $E_{cell}^{\circ} = 10.5 \ V$,$\frac{2.303 RT}{F} = 0.059$ at $298 \ K$)

  • A
    $1.385$
  • B
    $10.4115$
  • C
    $1.05$
  • D
    $1.0385$

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One half cell in a voltaic cell is constructed by dipping a silver rod in an $AgNO_3$ solution of unknown concentration, and the other half cell is a $Zn$ rod dipped in a $1 \text{ M}$ solution of $ZnSO_4$. $A$ voltage of $1.60 \text{ V}$ is measured at $298 \text{ K}$ for this cell. What is the concentration of $Ag^+$ ions in terms of $\log x$ (where $x = [Ag^+]$)? Given: $E^\ominus_{Zn^{2+}/Zn} = -0.76 \text{ V}$, $E^\ominus_{Ag^+/Ag} = +0.80 \text{ V}$, and $\frac{2.303RT}{F} = 0.059 \text{ V}$.

The $EMF$ of the following three galvanic cells are $E_1, E_2$ and $E_3$ respectively. Which of the following is correct?
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$(iii)$ $Zn | Zn^{2+} (0.1 \ M) || Cu^{2+} (1 \ M) | Cu$

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$Cu_{(s)} | Cu^{+2}(aq, 10^{-3} M) || Ag^{+}(aq, 10^{-5} M) | Ag_{(s)}$
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