Find the rate law for the reaction,$CHCl_{3(g)} + Cl_{2(g)} \rightarrow CCl_{4(g)} + HCl_{(g)}$ if the order of reaction with respect to $CHCl_{3(g)}$ is $1$ and with respect to $Cl_{2(g)}$ is $1/2$.

  • A
    Rate $= k[CHCl_3][Cl_2]^{1/2}$
  • B
    Rate $= k[CHCl_3]^2[Cl_2]^{1/2}$
  • C
    Rate $= k[CHCl_3]^{3/2}[Cl_2]$
  • D
    Rate $= k[CHCl_3]^{1/2}[Cl_2]$

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The data for the reaction $A + B \to C$ is given below. The rate law corresponding to the above data is:
$Exp.$ $[A]_0$ $[B]_0$ Initial rate
$(1)$ $0.012$ $0.035$ $0.10$
$(2)$ $0.024$ $0.070$ $0.80$
$(3)$ $0.024$ $0.035$ $0.10$
$(4)$ $0.012$ $0.070$ $0.80$

For the reaction $2NO + Cl_2 \rightarrow 2NOCl$,the following mechanism is proposed. What will be the rate law for the reaction? $NO + Cl_2 \rightleftharpoons NOCl_2$ (fast); $NOCl_2 + NO \rightarrow 2NOCl$ (slow)

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For the reaction $2NO_{(g)} + O_{2_{(g)}} \rightarrow 2NO_{2_{(g)}}$,the volume of the reaction vessel is suddenly reduced to half of its original volume. If the reaction is first order with respect to $O_2$ and second order with respect to $NO$,the rate of the reaction will:

Which one of the following is wrongly matched?

What is the unit of the rate constant for a $4^{th}$ order reaction?

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