For a reaction,$A \rightleftharpoons P$,the plots of $[A]$ and $[P]$ with time at temperatures $T_1$ and $T_2$ are given below. If $T_2 > T_1$,the correct statement$(s)$ is (are) (Assume $\Delta H^{\ominus}$ and $\Delta S^{\ominus}$ are independent of temperature and ratio of $\ln K$ at $T_1$ to $\ln K$ at $T_2$ is greater than $T_2 / T_1$. Here $H, S, G$ and $K$ are enthalpy,entropy,Gibbs energy and equilibrium constant,respectively.)
$(A)$ $\Delta H^{\ominus} < 0, \Delta S^{\ominus} < 0$
$(B)$ $\Delta G^{\ominus} < 0, \Delta H^{\ominus} > 0$
$(C)$ $\Delta G^{\ominus} < 0, \Delta S^{\ominus} < 0$
$(D)$ $\Delta G^{\ominus} < 0, \Delta S^{\ominus} > 0$

  • A
    $A, B$
  • B
    $A, C$
  • C
    $A, D$
  • D
    $A, B, C$

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The following lists contain reactions and their corresponding equilibrium constants at different temperatures:
List-$I$ (Reaction) List-$II$ $(K_p)$
$2 SO_{2(g)} + O_{2(g)} \rightleftharpoons 2 SO_{3(g)}$ at $298 \ K$ $4.0 \times 10^{24}$
$2 SO_{2(g)} + O_{2(g)} \rightleftharpoons 2 SO_{3(g)}$ at $700 \ K$ $3.0 \times 10^{4}$
$N_2O_{4(g)} \rightleftharpoons 2 NO_{2(g)}$ at $298 \ K$ $0.98$
$N_2O_{4(g)} \rightleftharpoons 2 NO_{2(g)}$ at $500 \ K$ $1700$

If $\Delta H_1^0$ and $\Delta H_2^0$ are the standard enthalpies for the reactions $2 SO_{2(g)} + O_{2(g)} \rightleftharpoons 2 SO_{3(g)}$ and $N_2O_{4(g)} \rightleftharpoons 2 NO_{2(g)}$ respectively, then:

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