For an electrochemical cell
$Sn_{(s)} | Sn^{2+}(aq, 1 \ M) || Pb^{2+}(aq, 1 \ M) | Pb_{(s)}$
the ratio $\frac{[Sn^{2+}]}{[Pb^{2+}]}$ when this cell attains equilibrium is
(Given $E^{0}_{Sn^{2+}/Sn} = -0.14 \ V$,$E^{0}_{Pb^{2+}/Pb} = -0.13 \ V$,$\frac{2.303 \ RT}{F} = 0.06$)

  • A
    $2.15$
  • B
    $3.33$
  • C
    $1.67$
  • D
    $4.33$

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Consider a Daniell cell operating under non-standard state conditions. Suppose that the cell's reaction is multiplied by $2$. Which of the following will double its initial value?

The $e.m.f.$ of the following galvanic cells are represented by $E_1, E_2, E_3$ and $E_4$. Which of the following statements is true?
$(i)$ $Zn|Zn^{2+} (1 \, M)||Cu^{2+} (1 \, M)|Cu$
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The change in electrode potential of $Cr^{3+}/Cr_2O_7^{2-}$ electrode at $25 \ ^oC$ due to change in $pH$ of its electrolytic solution from $1$ to $3$ is ........... $V$ (Assume: $[Cr_2O_7^{2-}]$ and $[Cr^{3+}]$ remain constant). Use: $\frac{2.303RT}{F} = 0.06$.

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