For the reaction $2 Cl ( g ) \rightarrow Cl _{2}( g )$,the correct option is

  • A
    $\Delta_{ r } H < 0$ and $\Delta_{ r } S < 0$
  • B
    $\Delta_{ r } H > 0$ and $\Delta_{ r } S > 0$
  • C
    $\Delta_{ r } H > 0$ and $\Delta_{ r } S < 0$
  • D
    $\Delta_{ r } H < 0$ and $\Delta_{ r } S > 0$

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At constant volume,$5 \, mol$ of a gas shows an increase in temperature by $3.5 \, K$ upon providing $437.5 \, J$ of heat. What will be the molar heat capacity for the gas at constant pressure in $J \, K^{-1} \, mol^{-1}$?

Consider the following statements:
Statement-$I$: Both internal energy $(U)$ and work $(w)$ are state functions.
Statement-$II$: During the free expansion of an ideal gas into vacuum,the work done is zero.
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