Given $E_{Fe^{3+}/Fe^{2+}}^{\circ} = +0.76 \ V$ and $E_{I_{2}/I^{-}}^{\circ} = +0.55 \ V$. The equilibrium constant for the reaction taking place in a galvanic cell consisting of the above two electrodes is (Given $\frac{2.303 \ RT}{F} = 0.06 \ V$)

  • A
    $1 \times 10^{7}$
  • B
    $1 \times 10^{9}$
  • C
    $3 \times 10^{8}$
  • D
    $5 \times 10^{12}$

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Given the values of $ᴧ^{0}$ for $KCl, KNO_3, HCl, NaOAc,$ and $NaCl$ are $149.9, 146.0, 426.2, 91.0,$ and $226.5 \, S \, cm^2 \, eq^{-1}$ respectively,calculate the value of $ᴧ^{0}$ for $HOAc$.

At $300 \ K$,the $E_{cell}^{\circ}$ of $A_{(s)} + B^{2+}_{(aq)} \rightleftharpoons A^{2+}_{(aq)} + B_{(s)}$ is $1.0 \ V$. If $\Delta_r S^{\circ}$ of this reaction is $100 \ J \ K^{-1} \ mol^{-1}$,what is $\Delta_r H^{\circ}$ (in $kJ \ mol^{-1}$) of this reaction? $(F = 96500 \ C \ mol^{-1})$

The conductivity of $0.001028 \, mol \, L^{-1}$ acetic acid is $4.95 \times 10^{-5} \, S \, cm^{-1}$. Calculate its dissociation constant if $\Lambda_m^\circ$ for acetic acid is $390.5 \, S \, cm^2 \, mol^{-1}$.

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Consider the following redox reaction :
$MnO_4^{-} + H^{+} + H_2C_2O_4 \rightleftharpoons Mn^{2+} + H_2O + CO_2$
The standard reduction potentials are given as below $(E_{red}^{\circ})$ :
$E_{MnO_4^{-} / Mn^{2+}}^{\circ} = +1.51 \ V$
$E_{CO_2 / H_2C_2O_4}^{\circ} = -0.49 \ V$
If the equilibrium constant of the above reaction is given as $K_{eq} = 10^x$,then the value of $x = $ . . . . . . (nearest integer).

$A$ battery is made from $Cr$ and $Na_2Cr_2O_7$. When this battery discharges according to the reaction $Na_2Cr_2O_7 + Cr + H^{+} \rightarrow Cr^{3+} + H_2O + Na^{+}$,the chemical equation is unbalanced. If $1 \ F$ (Faraday) of electricity is passed during the charging of the battery,what is the number of moles of $Cr^{3+}$ removed from the solution (in $/3$)?

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