Given below are two statements:
Statement $I$: In the oxalic acid vs $KMnO_4$ (in the presence of dil. $H_2SO_4$) titration,the solution needs to be heated initially to $60^{\circ}C$,but no heating is required in Ferrous Ammonium Sulphate $(\text{FAS})$ vs $KMnO_4$ titration (in the presence of dil. $H_2SO_4$).
Statement $II$: In oxalic acid vs $KMnO_4$ titration,the initial formation of $MnSO_4$ takes place at high temperature,which then acts as a catalyst for the further reaction. In the case of $\text{FAS}$ vs $KMnO_4$,heating oxidizes $Fe^{2+}$ into $Fe^{3+}$ by oxygen of air and error may be introduced in the experiment.
In the light of the above statements,choose the correct answer from the options given below:

  • A
    Statement $I$ is false but Statement $II$ is true
  • B
    Both Statement $I$ and Statement $II$ are true
  • C
    Statement $I$ is true but Statement $II$ is false
  • D
    Both Statement $I$ and Statement $II$ are false

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The amount of oxalic acid in a solution can be determined by titration with $KMnO_4$ in the presence of $H_2SO_4$. If the titration is performed in the presence of $HCl$,the results are unsatisfactory because $HCl$ ...

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