The heat required to convert $1 \, g$ of ice at $0^{\circ}C$ into steam at $100^{\circ}C$ is (given $L_{f} = 80 \, cal/g$,$c_{w} = 1 \, cal/g^{\circ}C$,$L_{v} = 536 \, cal/g$):

  • A
    $100 \, calorie$
  • B
    $0.01 \, kilocalorie$
  • C
    $716 \, calorie$
  • D
    $1 \, kilocalorie$

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Answer the following questions based on the $P$ - $T$ phase diagram of carbon dioxide:
$(a)$ At what temperature and pressure can the solid,liquid and vapour phases of $CO_{2}$ co-exist in equilibrium?
$(b)$ What is the effect of decrease of pressure on the fusion and boiling point of $CO_{2}$?
$(c)$ What are the critical temperature and pressure for $CO_{2}$? What is their significance?
$(d)$ Is $CO_{2}$ solid,liquid or gas at $(i)$ $-70^{\circ}C$ under $1\;atm$,$(ii)$ $-60^{\circ}C$ under $10\;atm$,$(iii)$ $15^{\circ}C$ under $56\;atm$?

$A$ lead bullet at $27^{\circ}C$ just melts when stopped by an obstacle. Assuming that $25\%$ of the heat produced is absorbed by the obstacle,find the velocity of the bullet at the time of striking in $m/s$. (Melting point of lead $= 327^{\circ}C$,specific heat of lead $= 0.03 \, cal/g^{\circ}C$,latent heat of fusion of lead $= 6 \, cal/g$,and $J = 4.2 \, J/cal$)

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