If a solute associates in a solvent, its experimentally calculated molar mass using the boiling point elevation method will be

The experimental molecular mass of acetic acid dissolved in benzene will be ........ (Assume complete association).

Acetic acid dissolved in benzene shows a molecular mass of

$2 \ g$ of benzoic acid $(M_w = 122 \ g/mol)$ dissolved in $25 \ g$ of $C_6H_6$ shows a depression in freezing point equal to $1.62 \ K$. Given $K_f (C_6H_6) = 4.9 \ K \ kg \ mol^{-1}$. If the acid forms a dimer in the solution,then the percentage association of the acid is $......... \%$.

$A$ molecule $M$ associates in a given solvent according to the equation $M \rightleftharpoons (M)_n$. For a certain concentration of $M,$ the van't Hoff factor was found to be $0.9$ and the fraction of associated molecules was $0.2.$ The value of $n$ is

Calculate the van't Hoff factor $(i)$ for an aqueous solution of $0.02 \text{ m}$ formic acid if it freezes at $-0.045^{\circ}\text{C}$. Given: $K_f = 1.86 \text{ K kg mol}^{-1}$ and the freezing point of pure water $= 0^{\circ}\text{C}$.