In an adiabatic expansion of an ideal gas,which of the following relations holds true?

$1 \, \text{mole}$ of an ideal gas is allowed to expand reversibly and adiabatically from a temperature of $27^{\circ}C$. The work done is $3 \, \text{kJ} \, \text{mol}^{-1}$. The final temperature of the gas is $...... \text{K}$ (Nearest integer). Given $C_{V} = 20 \, \text{J} \, \text{mol}^{-1} \, \text{K}^{-1}$.

Calculate the change in internal energy $(\Delta U)$ if $\Delta H = -92.2\, kJ$,$P = 40\, atm$,and $\Delta V = -1\, L$.

$A$ sample of gas absorbs $4000 \ kJ$ of heat and the surrounding does $2000 \ J$ of work on the sample. What is the value of $\Delta U$ (in $kJ$)?

Explain the relationship between the change in heat at constant pressure and constant volume.

For $1 \, \text{mol}$ of an ideal gas,isothermal expansion occurs from $1 \, \text{L}$ to $10 \, \text{L}$ in a vacuum at $300 \, \text{K}$. What is the value of $\Delta U$ for this process? $(R = 2 \, \text{cal} \, \text{K}^{-1} \, \text{mol}^{-1})$