In order to oxidize a mixture of $1 \text{ mole}$ each of $FeC_2O_4$, $Fe_2(C_2O_4)_3$, $FeSO_4$, and $Fe_2(SO_4)_3$ in an acidic medium, the number of moles of $KMnO_4$ required is:

  • A
    $3$
  • B
    $2$
  • C
    $5$
  • D
    $7$

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Identify the redox reactions among the following and determine the oxidizing and reducing agents in them:
$(a) 3HCl_{(aq)} + HNO_{3_{(aq)}} \to Cl_{2_{(g)}} + NOCl_{(g)} + 2H_2O_{(l)}$
$(b) HgCl_{2_{(aq)}} + 2KI_{(aq)} \to HgI_{2_{(s)}} + 2KCl_{(aq)}$
$(c) Fe_2O_{3_{(s)}} + 3CO_{(g)} \xrightarrow{\Delta} 2Fe_{(s)} + 3CO_{2_{(g)}}$

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$x, y$ and $z$ are respectively:
$MnO_4^- + x e^- \xrightarrow{\text{Alkaline medium}} MnO_4^{2-}$
$MnO_4^- + y e^- \xrightarrow{\text{Acidic medium}} Mn^{2+}$
$MnO_4^- + z e^- \xrightarrow{\text{Neutral medium}} MnO_2$

Difficult
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Match List-$I$ with the List-$II$.
List-$I$ (Reaction) List-$II$ (Type of redox reaction)
$A$. $N_{2(g)} + O_{2(g)} \rightarrow 2 NO_{(g)}$ $I$. Decomposition
$B$. $2 Pb(NO_3)_{2(s)} \rightarrow 2 PbO_{(s)} + 4 NO_{2(g)} + O_{2(g)}$ $II$. Displacement
$C$. $2 Na_{(s)} + 2 H_2 O_{(l)} \rightarrow 2 NaOH_{(aq)} + H_{2(g)}$ $III$. Disproportionation
$D$. $2 NO_{2(g)} + 2 OH^-_{(aq)} \rightarrow NO^-_{2(aq)} + NO^-_{3(aq)} + H_2 O_{(l)}$ $IV$. Combination

Choose the correct answer from the options given below:

Ferrous sulphate on strong heating gives:

Hot concentrated sulphuric acid is a moderately strong oxidizing agent. Which of the following reactions does not show oxidizing behaviour?

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