In the Carius method, $0.2425 \ g$ of an organic compound gave $0.5253 \ g$ of silver chloride. The percentage of chlorine in the organic compound is: (in $\%$)

  • A
    $53.58$
  • B
    $87.65$
  • C
    $37.57$
  • D
    $34.79$

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Describe the Kjeldahl's method and the principles for the estimation of nitrogen present in an organic compound.

$0.25 \ g$ of an organic compound containing chlorine gave $0.40 \ g$ of silver chloride in Carius estimation. The percentage of chlorine present in the compound is $.....$ [in nearest integer].
(Given: Molar mass of $Ag$ is $108 \ g \ mol^{-1}$ and that of $Cl$ is $35.5 \ g \ mol^{-1}$)

In an estimation of sulphur by Carius method, $0.2 \text{ g}$ of the substance gave $0.6 \text{ g}$ of $BaSO_4$. The percentage of sulphur in the substance is . . . . . . %. (Given molar mass in $\text{g mol}^{-1}$: $S = 32$, $BaSO_4 = 233$)

In the $Kjeldahl$ method,when an organic compound containing nitrogen is heated with concentrated $H_2SO_4$,nitrogen is converted into which of the following?

Zeisel method is used to estimate

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